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Co-pyrolysis of oil sludge with hydrogen-rich plastics in a vertical stirring reactor: Kinetic analysis, emissions, and products

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 10, doi: 10.1007/s11783-022-1570-3

Abstract:

● Collaborative treatment of plastics and OS was established to improve oil quality.

Keywords: Oily sludge     Pyrolysis     Polyethylene     H/C<sub>effsub> ratio     Oil quality    

A density functional theory study of methane activation on MgO supported NiM cluster: role of M on CH

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 10,   Pages 1485-1492 doi: 10.1007/s11705-022-2169-8

Abstract: The role of M on the first CH bond cleavage of CH<sub>4sub> was investigated.Doping elements of the same period in Ni cluster, such as Fe, Co and Cu, for CH bond activation followsAs a result, Ni–Fe shows the best ability for CH bond cleavage.Consequently, CH bond activation demands a lower energy barrier on Ni–Pt cluster.>4sub> raises with the CH<sub>4sub> electron gain increasing.

Keywords: CH<sub>4sub> dissociation     Ni–M     CH bond activation     charge transfer    

H<sub>∞sub> control in the frequency domain for a semi-active floor isolation system

Yundong SHI, Tracy C BECKER, Masahiro KURATA, Masayoshi NAKASHIMA

Frontiers of Structural and Civil Engineering 2013, Volume 7, Issue 3,   Pages 264-275 doi: 10.1007/s11709-013-0214-x

Abstract: A floor isolation system installed in a single floor or room in a fixed base structure is designed to protect equipment. With this configuration, the input motions to the floor isolation from the ground motions are filtered by the structure, leaving the majority of the frequency content of the input motion lower than the predominant frequency of the structure. The floor isolation system should minimize the acceleration to protect equipment; however, displacement must also be limited to save floor space, especially with long period motion. Semi-active control with an control was adopted for the floor isolation system and a new input shaping filter was developed to account for the input motion characteristics and enhance the effectiveness of the control. A series of shake table tests for a semi-active floor isolation system using rolling pendulum isolators and a magnetic-rheological damper were performed to validate the control. Passive control using an oil damper was also tested for comparison. The test results show that the control effectively reduced acceleration for short period motions with frequencies close to the predominant frequency of the structure, as well as effectively reduced displacement for long period motions with frequencies close to the natural frequency of the floor isolation system. The control algorithm proved to be more advantageous than passive control because of its capacity to adjust control strategies according to the different motion frequency characteristics.

Keywords: semi-active     floor isolation     H<sub>∞sub> control     MR damper     shaping filter     shaking table    

encapsulating M(Co, Fe)-Ni alloy for electrochemical production of syngas with potential-independent CO/H

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 4,   Pages 498-510 doi: 10.1007/s11705-021-2082-6

Abstract: The electrochemical conversion of CO<sub>2sub>-H<sub>2sub>O into CO-H<sub>2sub> using renewableLow-cost electrocatalysts to produce tunable syngas with a potential-independent CO/H<sub>2sub> ratioConsequently, syngas with a wide range of CO/H<sub>2sub> ratios, from 0.5:1 to 3.4:1, can be producedMore importantly, stable CO/H<sub>2sub> ratios of 2:1 and 1.5:1, corresponding to the ratio to producesub>2sub> ratio from electrochemical CO<sub>2sub> reduction.

Keywords: electrochemical reduction of CO<sub>2sub>     syngas     N-doped carbon nanotubes     encapsulated alloynanoparticles     CO/H<sub>2sub> ratio    

New insight into effect of potential on degradation of Fe-N-C catalyst for ORR

Yanyan GAO, Manman QI, Liang HE, Haiping CHEN, Wenzhe LUO, Ming HOU, Zhigang SHAO

Frontiers in Energy 2021, Volume 15, Issue 2,   Pages 421-430 doi: 10.1007/s11708-021-0727-2

Abstract: In recent years, Fe-N-C catalyst is particularly attractive due to its high oxygen reduction reactionHowever, the durability problems still pose challenge to the application of Fe-N-C catalyst.Although considerable work has been done to investigate the degradation mechanisms of Fe-N-C catalystIn fact, the 2e pathway in the ORR process of Fe-N-C catalyst would result in the formation of H O ,by quantifying the H O intermediate.

Keywords: proton exchange membrane fuel cells (PEMFCs)     oxygen reduction reaction (ORR)     Fe-N-C catalyst     potential     H<sub>2sub>O<sub>2sub>     degradation    

Persulfate-Induced Three Coordinate Nitrogen (N3<sub>Csub>) Vacancies in Defective Carbon Nitride forEnhanced Photocatalytic H<sub>2sub>O<sub>2sub> Evolution Article

Wei Miao, Yijie Wang, Ying Liu, Hehe Qin, Chengcheng Chu, Shun Mao

Engineering 2023, Volume 25, Issue 6,   Pages 214-221 doi: 10.1016/j.eng.2021.12.016

Abstract:

In-situ photocatalytic H<sub>2sub>O<sub>2sub> production has been receiving increasing attentionin recent years for sustainable H<sub>2sub>O<sub>2sub> synthesis.photocatalysts for H<sub>2sub>O<sub>2sub> evolution.H<sub>2sub>O<sub>2sub> production.The photocatalytic H<sub>2sub>O<sub>2sub> evolution from the N3<sub>Csub>-rich g-C<sub>3sub>N

Keywords: Carbon nitride     N3<sub>Csub> vacancy     Hydrogen peroxide evolution     Photocatalysis     Persulfate    

Robust Metal–Organic Frameworks with High Industrial Applicability in Efficient Recovery C<sub>3sub>H<sub>8sub> and C<sub>2sub>H<sub>6sub> from Natural Gas Upgrading Article

Shikai Xian, Junjie Peng, Haardik Pandey, Timo Thonhauser, Hao Wang, Jing Li

Engineering 2023, Volume 23, Issue 4,   Pages 56-63 doi: 10.1016/j.eng.2022.07.017

Abstract: sub>2sub>H<sub>6sub> and C<sub>3sub>H<sub>8sub> from natural gas is an important but challengingsub>3sub>H<sub>8sub> and C<sub>2sub>H<sub>6sub>, giving rise to the high loading capacity andselectivity for C<sub>3sub>H<sub>8sub> and C<sub>2sub>H<sub>6sub>.sub>3sub>H<sub>8sub>/C<sub>2sub>H<sub>6sub>/CH<sub>4sub> has been demonstrated by ternary breakthroughsub>2sub>H<sub>6sub> and C<sub>3sub>H<sub>8sub>.

Keywords: Metal–     organic framework     Hydrocarbon adsorption and separation     Selectivity     Stability     Scale-up synthesis    

Development of H<sub>2sub>O/CO<sub>2sub> co-electrolysis in solid oxide electrolysis cell

Fan Hui,Song Shidong,Han Minfang

Strategic Study of CAE 2013, Volume 15, Issue 2,   Pages 107-112

Abstract:

Solid oxide electrolysis cell (SOEC) as an environmental-friendly device can converse the electric energy into chemical energy with high efficiency. In this paper, the progress on structure and working principle of SOEC for co-electrolyzing steam and carbon dioxide to generate syngas were reviewed. The structure of SOEC, the recent development of high temperature steam/CO2 co-electrolysis from solid oxide single electrolysis cell and cell stack were also introduced. In addition, the improvement of structure and development of novel material for increasing the electrolysis efficiency of SOEC were put forward as well.

Keywords: SOEC     H<sub>2sub>O/CO<sub>2sub> co-electrolysis     syngas     electrolysis efficiency     water electrolysis    

NO<sub>xsub> and H<sub>2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

Frontiers in Energy 2021, Volume 15, Issue 1,   Pages 4-13 doi: 10.1007/s11708-020-0804-y

Abstract: China to control NO emission; thus, it is necessary to understand the formation mechanism of NO and HThis paper focused on the investigation of reductive gases in the formation of NO and H S in the reductiveGE) coal and their blends with different mixing ratios were conducted in a drop tube furnace at 1200°C–1400°C with an excessive air ratio of 0.6–1.2.temperature and a decrease in the excessive air ratio.

Keywords: blended coal combustion     NO<sub>x sub>formation     H<sub>2sub>S formation     air staged combustion    

An investigation of reaction furnace temperatures and sulfur recovery

S. ASADI, M. PAKIZEH, M. POURAFSHARI CHENAR

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 3,   Pages 362-371 doi: 10.1007/s11705-011-1106-z

Abstract: In a modern day sulfur recovery unit (SRU), hydrogen sulfide (H S) is converted to elemental sulfur usingThe effect of the H S concentration, the H S/CO ratio, the input air flow rate, the acid gas flow ofAlso the effects of the tail gas ratio and the catalytic bed type on the sulfur recovery were studiedHowever, if three other parameters (the concentration of H S, the ratio H S/CO and the flow rate ofand these conditions are a minimum temperature of 300°C, a ratio of 2.0 and a hydrolysing Claus bed.

Keywords: Claus unit     concentration of H<sub>2sub>S     tail gas ratio     sulfur recovery     catalytic bed    

growth of a-few-layered MoS on CdS nanorod for high efficient photocatalytic H production

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 752-759 doi: 10.1007/s11708-021-0779-3

Abstract: An ultrathin MoS<sub>2sub> was grown on CdS nanorod by a solid state method using sulfur powder assulfur source for photocatalytic H<sub>2sub> production.The characterization result reveals that the ultrathin MoS<sub>2sub> nanosheets loaded on CdS has aThe photoelectrochemical result shows that MoS<sub>2sub> not only are beneficial for charge separation542 μmol/h, which is 6 times of that on pure CdS (92 μmol/h).

Keywords: photocatalytic H<sub>2sub> production     CdS     MoS<sub>2sub> cocatalyst     charge separation    

Removal of P<sub>4sub>, PH<sub>3sub> and H<sub>2sub>S from Yellow Phosphoric Tail Gas by a Catalytic

Ning Ping,Hans-Jörg Bart,Wang Xueqian,Ma Liping,Chen Liang

Strategic Study of CAE 2005, Volume 7, Issue 6,   Pages 27-35

Abstract: and activated carbon proved to be effective catalysts in the catalytic oxidation process (COP) for H<sub>2sub>S and PH<sub>3sub> removal.

Keywords: catalyst     catalytic oxidation     H<sub>2sub>S     P<sub>4sub>     PH<sub>3sub>     fixed bed    

Photoelectrocatalytic generation of H and S from toxic HS by using a novel BiOI/WO nanoflake array photoanode

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 744-751 doi: 10.1007/s11708-021-0775-7

Abstract: In this paper, a photoelectrocatalytic (PEC) recovery of toxic H<sub>2sub>S into H<sub>2sub> andmml:msubsup> catalytic system, the PEC system toward splitting of HH<sub>2sub> was simultaneously generated at a rate of about 0.867 mL/(h·cm).The proposed PEC H<sub>2sub>S splitting system provides an efficient and sustainable route to recoverH<sub>2sub> and S.

Keywords: bismuth oxyiodide (BiOI)/ tungsten trioxide (WO<sub>3sub>) nano-flake arrays (NFA)     photoelectrocatalytic(PEC)     H<sub>2sub>S splitting     H<sub>2sub>     S    

Nickel(II) ion-intercalated MXene membranes for enhanced H<sub>2sub>/CO<sub>2sub> separation

Yiyi Fan, Jinyong Li, Saidi Wang, Xiuxia Meng, Yun Jin, Naitao Yang, Bo Meng, Jiaquan Li, Shaomin Liu

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 4,   Pages 882-891 doi: 10.1007/s11705-020-1990-1

Abstract: A membrane-assisted separation is promising in producing high-purity H .The prepared membranes showed excellent H /CO mixture separation performance at room temperature.Compared with the original Ti C T /Al O hollow fiber membranes, the permeation of hydrogen through theNi -Ti C T /Al O membrane was considerably increased, stemming from the strong interaction betweenOur results indicate that the Ni tailored Ti C T /Al O hollow fiber membranes can inspire promising

Keywords: MXene     H<sub>2sub>/CO<sub>2sub> separation     nickel ions     hollow fiber    

grown TiN/N-TiO composite for enhanced photocatalytic H evolution activity

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 721-731 doi: 10.1007/s11708-021-0766-8

Abstract: Titanium nitride (TiN) decorated N-doped titania (N-TiO<sub>2sub>) composite (TiN/N-TiO<sub>2sub>) is fabricated via an in situ nitridation using a hydrothermally synthesized TiO<sub>2sub>After the optimization of the reaction condition, the resultant TiN/N-TiO<sub>2sub> composite deliversa hydrogen evolution activity of up to 703 μmol/h under the full spectrum irradiation of Xe-lamp, whichis approximately 2.6 and 32.0 times more than that of TiO<sub>2sub> and TiN alone, respectively.

Keywords: photocatalytic H<sub>2sub> evolution     TiN/N-TiO<sub>2sub> composite     plasmonic effect     in-situ    

Title Author Date Type Operation

Co-pyrolysis of oil sludge with hydrogen-rich plastics in a vertical stirring reactor: Kinetic analysis, emissions, and products

Journal Article

A density functional theory study of methane activation on MgO supported NiM cluster: role of M on CH

Journal Article

H<sub>∞sub> control in the frequency domain for a semi-active floor isolation system

Yundong SHI, Tracy C BECKER, Masahiro KURATA, Masayoshi NAKASHIMA

Journal Article

encapsulating M(Co, Fe)-Ni alloy for electrochemical production of syngas with potential-independent CO/H

Journal Article

New insight into effect of potential on degradation of Fe-N-C catalyst for ORR

Yanyan GAO, Manman QI, Liang HE, Haiping CHEN, Wenzhe LUO, Ming HOU, Zhigang SHAO

Journal Article

Persulfate-Induced Three Coordinate Nitrogen (N3<sub>Csub>) Vacancies in Defective Carbon Nitride forEnhanced Photocatalytic H<sub>2sub>O<sub>2sub> Evolution

Wei Miao, Yijie Wang, Ying Liu, Hehe Qin, Chengcheng Chu, Shun Mao

Journal Article

Robust Metal–Organic Frameworks with High Industrial Applicability in Efficient Recovery C<sub>3sub>H<sub>8sub> and C<sub>2sub>H<sub>6sub> from Natural Gas Upgrading

Shikai Xian, Junjie Peng, Haardik Pandey, Timo Thonhauser, Hao Wang, Jing Li

Journal Article

Development of H<sub>2sub>O/CO<sub>2sub> co-electrolysis in solid oxide electrolysis cell

Fan Hui,Song Shidong,Han Minfang

Journal Article

NO<sub>xsub> and H<sub>2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

Journal Article

An investigation of reaction furnace temperatures and sulfur recovery

S. ASADI, M. PAKIZEH, M. POURAFSHARI CHENAR

Journal Article

growth of a-few-layered MoS on CdS nanorod for high efficient photocatalytic H production

Journal Article

Removal of P<sub>4sub>, PH<sub>3sub> and H<sub>2sub>S from Yellow Phosphoric Tail Gas by a Catalytic

Ning Ping,Hans-Jörg Bart,Wang Xueqian,Ma Liping,Chen Liang

Journal Article

Photoelectrocatalytic generation of H and S from toxic HS by using a novel BiOI/WO nanoflake array photoanode

Journal Article

Nickel(II) ion-intercalated MXene membranes for enhanced H<sub>2sub>/CO<sub>2sub> separation

Yiyi Fan, Jinyong Li, Saidi Wang, Xiuxia Meng, Yun Jin, Naitao Yang, Bo Meng, Jiaquan Li, Shaomin Liu

Journal Article

grown TiN/N-TiO composite for enhanced photocatalytic H evolution activity

Journal Article